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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 8, Number 6
BKCSDE 8(6)
June 20, 1987 

 
Title
Temperature Dependence of the Vibration-Vibration Energy Transfer in the Deexcitaion of NO(2) by NO(0)
Author
Jongbaik Ree*, Chang-Kook Sohn, Chang Soon Lee, Yoo Hang Kim
Keywords
Abstract
The temperature dependence of the vibrational relaxation of NO(= 2) by NO(v = 0) has been investigated over the temperature range 100-3000 K. We have assumed that the deexcitation of NO(2) by NO(0) undergoes vibration-to-vibration (VV) energy exchange with the transfer of the energy mismatch ΔE through rotation (R) and translation(T). The relaxation rate constants are calculated by solving the time-dependent Schrodinger equation. The sum of V-V, T, and V-V, R contributions shows very weak temperature dependence and is in reasonable agreement with observed data over the temperature range 300-3000 K.
Page
449 - 453
Full Text
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