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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 8, Number 4
BKCSDE 8(4)
April 20, 1987 

 
Title
Palladium Dichloro Complex Catalysed Oxidation of Cyclopentene by Dioxygen in Tetralin
Author
Katsuomi Takehira, Takashi Hayakawa*, Hideo Orita, Masao Shimizu, In Hwan Oh
Keywords
Abstract
Palladium dichloro complexes catalysed the oxidation of cyclopentene by dioxygen in tetralin solvent at ambient temperature. Cyclopentanone formed mainly together with autoxidation products from both cyclopentene and tetralin. The oxidation seems to proceed by co-oxidation mechanism, where tetralin was first oxidized to its hydroperoxide which then oxidized cyclopentene to cyclopentanone. Mechanism of the other by-products formations has been discussed.
Page
254 - 257
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