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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 8, Number 4
BKCSDE 8(4)
April 20, 1987 

 
Title
Thermodynamic Analysis of the Hammett Reaction Parameter and Free Energy Relationship for the Pressure Change
Author
Jung-Ui Hwang
Keywords
Abstract
Pressure dependance of Hammett reaction parameter was analyzed and the free energy relationship for the pressure change derived thermodynamically. There are insufficient data in the literature to test the relation derived but from some limited previous data it could be concluded that the parameter ρ is dependent on pressure and increase or decrease as pressure increase for a given reaction series.
Page
237 - 242
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