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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 8, Number 3
BKCSDE 8(3)
March 20, 1987 

 
Title
Cross Interaction Between Identical Groups
Author
Ikchoon Lee
Keywords
Abstract
Various useful relations involving Hammett's and Brønsted's coefficients are derived for cross interactions between identical groups: ρii = ρN + ρL, ρL - ρN = 1, βii = βN + βL and βN - βL = 1. The use of these relations enable us to correctly interprete the transition state structure. Another advantage of the use of these relations is to use ρ/ρe for the determination of corresponding β values instead of plotting log k vs pKlg, once ρe values for standardizing equilibria are obtained.
Page
200 - 202
Full Text
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