KCS Publications

HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 8, Number 3
BKCSDE 8(3)
March 20, 1987

Title	1,4-Dicyanobutene Bridged Binuclear Iridium (Ⅰ, Ⅲ) Complexes and Their Catalytic Activities
Author	Hwa-Kun Park, Chong Shik Chin*
Keywords
Abstract	Reactions of Ir(CIO4)(CO)(PPh3)2 with dicyano olefins, cis-NCCH = CHCH2CH2CN (cDC1B), trans-NCCH = CHCH2CH2CN (tDC1B), trans-NCCH2CH = CHCH2CN (tDC2B), and NCCH2CH2CH2CH2CN (DCB) produce binuclear dicationic iridium (Ⅰ) complexes, [(CO)(PPh3)2Ir-NC-A-CN-Ir(PPh3)2(CO)](ClO4)2 (NC-A-CN = cDC1B (1a), tDC1B (1b), tDC2B (1c), DCB (1d)). Complexes 1a-1d react with hydrogen to give binuclear dicationic tetrahydrido iridium (Ⅲ ) complexes, [(CO)(PPh3)2(H)2Ir-NC-A-CN-Ir(H)2(PPh3)2(CO)]( ClO4)2 (NC-A-CN = cDC1B (2a), tDC1B (2b), tDC2B (2c), DCB (2d)). Complexes 2a and 2b catalyze the hydrogenation of cDC1B and tDC1B, respectively to give DCB, while the complex 2c is catalytically active for the isomerization of tDC2B to give cDC1B and tDC1B and the hydrogenation of tDC2B to give DCB at 100℃.
Page	185 - 189
Full Text	PDF

How to access to the WOL for The Bulletin of the Korean Chemical Society ?

The Bulletin of the Korean Chemical Society will be co-published with Wiley-VCH from 2015 towards. The online version of the Journal will thus be available on Wiley Online Library, Wiley(-VCH)'s global online platform.

KCS members can get a free online access to the Bulletin of the Korean Chemical Society in WOL.

Free Access to WOL