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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 8, Number 3
BKCSDE 8(3)
March 20, 1987 

 
Title
Preparation and Properties of New Metal-chain Compounds with Commensurate Peierls Structure
Author
Kuk Haeng Lee*, Ja Hong Kim, Masagi Mizuno
Keywords
Abstract
New platinum chain compounds, [M(en)2]0.80[Pt(ox)2]·2H2O where M = Cu or Pt, en = ethylenediamine and ox = oxalate, have been prepared and found to have a commensurate Peierls structure as evidenced by the five-fold Pt chain periodicity and unusually low electrical conductivity (1.5 × 10-5 ∼ 5.7 × 10-3 S/cm). Including two other compounds with the Peierls structure, their characteristic features were deduced and explained from the point of view of the band theory.
Page
137 - 140
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