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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 8, Number 2
BKCSDE 8(2)
February 20, 1987 

 
Title
Simulation of Temperature-Dependent EPR Spectra of Mixed-Valence Copper (Ⅱ)-Copper (Ⅰ)-Complexes
Author
Hyunsoo Soo
Keywords
Abstract
Temperature-dependent, solution EPR spectra of two mixed-valence copper(Ⅱ)-copper(Ⅰ) complexes have been simulated by using modified Bloch equations. The transition probability for the intramolecular electron transfer is determined from the simulation. The transition probabilities have been fitted to the Arrhenius equation to derive the activation energies. The transition probability also varies according to the solvent used.
Page
111 - 114
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