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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 7, Number 5
BKCSDE 7(5)
May 20, 1986 

 
Title
Cupric Complexes Produced from the Reaction of Cupric Nitrate Trihydrate with S-2-Pyridyl Thioates
Author
Young Nam Choi, Hyunsoo So*, Jae In Lee, Sunggak Kim
Keywords
Abstract
The reaction of cupric nitrate trihydrate with S-2-pyridyl thioates in acetonitrile was studied. The major products were the corresponding carboxylic acids and [Cu(NO3)(C5H4NS)(C5H5NS)] (Complex A). Sometimes [Cu(NO3) (C5H4NS) (H2O)] was also obtained in addition to Complex A. When Complex A was recrystallized in dimethylsulfoxide, [Cu(NO3) (C5H4NS) (C5H5NS) {(CH3)2SO}2 ]·2H2O was crystallized. The structures of these copper complexes and the role of cupric nitrate in the hydrolysis of S-2-pyridyl thioates are discussed.
Page
385 - 388
Full Text
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