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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 7, Number 5
BKCSDE 7(5)
May 20, 1986 

 
Title
Syntheses and Spectroscopic Studies of Metal-Metal Bonded Complexes (Zr-Fe)
Author
Jaejung Ko*
Keywords
Abstract
The preparation of the metal-metal bonded complex Cp2ZrClFeCp(CO)2 has been achieved by the reaction of Cp2ZrCl2 and strong nucleophile NaFeCp(CO)2. The more soluble metal-metal bonded complexes Cp2ZrRFeCp(CO)2(R = CH3, n-C8H17) have also been prepared through the reaction of Cp2ZrRCl and NaCpFe(CO)2. The complexes were characterized by IR, Raman, 1H NMR and Mass spectra. The complete absorption (100-3800 cm-1) spectra for the three metal-metal bonded molecules are reported and the bands of each vibration were assigned.
Page
334 - 337
Full Text
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