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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 7, Number 4
April 20, 1986 

Concentration Dependence of the ν1 Isotropic Raman Band of Nitromethane in Chloroform-d, Pyridine-d5, 1,3,5-Trifluorobenzene, and Hexafluorobenzene
Joong Chul Choe, Myung Soo Kim*
Concentration dependences of the isotropic Raman band width and the peak position for the ν1 (C-H stretching) mode of nitromethane in chloroform-d, pyridine-d5, 1,3,5-trifluorobenzene, and hexafluorobenzene have been investigated. For all solutions, the experimental concentration dependences have been well described by the concentration fluctuation model of Knapp and Fischer when appropriate values for the effective numbers (N) of nearest neighbors were used. For the CH3NO2/C6F6 solution, an abnormally small value (2) of N indicates strong intermolecular interaction.
275 - 279
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