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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 7, Number 1
BKCSDE 7(1)
January 20, 1986 

 
Title
Red Shift of the Raman (FBCARS) Excitation Profile of Iodine from the Absorption Spectrum(Ⅰ)
Author
Mu Sang Lee, L. A. Carreira
Keywords
Abstract
Folded Box coherent anti-Stokes Raman spectroscopy (FBCARS) spectra of the fundamental symmetric stretch(213 cm-1) and the first overtone(421 cm-1) of I2 have been recorded over the pump wavelength range from 495 nm to 580 nm. The lineshapes were fitted using the least squares method and the A and C term of CARS were calculated. From the fitting of A and C terms, the real(R) and imaginary(I) term intensity of CARS were calculated using harmonic oscillator program. The calculated CARS excitation profile of I2 with R and I term data was about 270 cm-1 red shifted from the absorption spectrum.
Page
59 - 62
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