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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 7, Number 1
BKCSDE 7(1)
January 20, 1986 

 
Title
Phase Transition and Approximated Integral Equation for Radial Distribution Function
Author
Byoung Jip Yoon, Mu Shik Jhon
Keywords
Abstract
A reduced condition for liquid-gas phase transition from the singularity of compressibility is derived using diagrammatic approach and is examined in the hard sphere system. The condition turns out that the Percus-Yevick and the Hyper-Netted-Chain approximation never conceive the idea of phase transition, and explains that the liquid-gas transition does not exist in hard sphere system. The solid-fluid transition is considered on the viewpoint of correlation function and diagrammatic analysis.
Page
20 - 23
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