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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 6, Number 2
BKCSDE 6(2)
February 20, 1985

Title	Photocycloaddition Reaction of trans-Cinnamonitrile Derivatives with Tetramethylethylene
Author	Myeong Yun Chae, Suk Kyoon Yoon, Sang Chul Shim
Keywords
Abstract	Stereospecific [2 + 2] cycloadducts are obtained as major products when trans-cinnamonitrile derivatives are irradiated with excess tetramethylethylene. The fluorescence quenching studies, weak exciplex fluorescence, and sensitization by benzophenone suggest that this stereospecific photochemical cycloaddition reaction involves singlet exciplex intermediate formed between cinnamonitrile derivatives and tetramethylethylene.
Page	95 - 98
Full Text	PDF

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