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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 5, Number 6
BKCSDE 5(6)
June 20, 1984 

 
Title
Study of Molecular Reorientation in Liquid with Raman Spectroscopy. Intermolecular Interaction fo Hexafluorobenzene with Benzene
Author
Hyun Jin Hwang, Kwan Kim, Myung Soo Kim
Keywords
Abstract
Raman spectroscopy was used to study the reorientational motion of hexafluorobenzene in benzene and also in neutral solvents. From the viscosity dependence of the reorientation time, intermolecular interaction in the systems was investigated. No evidence was found to support the presence of long-lived 1:1 complex of hexafluorobenzene and benzene. The unusual viscosity dependence of the reorientational motion observed in the systems was explained as due to the formation of transient complexes.
Page
245 - 248
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