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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 5, Number 6
BKCSDE 5(6)
June 20, 1984

Title	Reactions of Thianthrene Cation Radical Perchlorate with Free Radical. Ⅱ. On the Reaction with tert-Butyl Peroxide
Author	Jongheon Shin, Kyongtae Kim
Keywords
Abstract	Reaction of thianthrene cation radical perchlorate (1) with tert-butyl peroxide (TBP) in acetonitrile gave thianthrene (2), thianthrene 5-oxide (3), cis-thianthrene-5,10-dioxide (4), 5-acetonylthianthrenium perchlorate (9), along with small amount of thianthrene-5,5-dioxide (7) in some cases. Isolation of N-tert-butylacetamide indicated the formation of tert-butyl cation from TBP. The formation mechanisms of these products were proposed.
Page	211 - 215
Full Text	PDF

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