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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 5, Number 4
BKCSDE 5(4)
April 20, 1984 

 
Title
Evidence for Nitrogen-Bonded Acrylonitrile to Iridium (Ⅰ) in Acrylonitrilecarbonylbis(triphenylphosphie)iridium (Ⅰ) perchlorate
Author
Soonheum Park, Hwa-Kun Park, Chong Shik Chin
Keywords
Abstract
Analyses of 1H-NMR, infrared and electronic spectral data for [Ir(CH2 = CHCN)(CO)(P(C6H5)3)2]ClO4 (1) prepared by the reaction of Ir(OClO3)(CO)(P(C6H5)3)2 with CH2 = CHCN, agree with the suggestion that 1 is a mixture of the nitrogen-bonded acrylonitrile complex, [(CO)(P(C6H5)3)2Ir-NCCH = CH2]ClO4 and other compound which may be the C = C π -system-bonded acrylonitrile complex, [(CO)(P(C6H5)3)2Ir-CHCN = CH2]ClO4.
Page
167 - 169
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