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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 4, Number 5
BKCSDE 4(5)
May 20, 1983

Title	MO Theoretical Studies on Diels-Alder Reactions of α-Allenic Ketones
Author	Eun Sook Han, Ikchoon Lee, Byung Doo Chang
Keywords
Abstract	The Diels-Alder cycloaddition reactions between dienes and allenic ketones were studied theoretically using CNDO/2 method. It was found that the reaction is a neutral electron demand type with matrix element control and the reactivity, the regio- and stereo-selectivities can be correctly predicted based on interaction energies calculated with the 4-center FMO formalism.
Page	197 - 200
Full Text	PDF

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