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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 3, Number 3
BKCSDE 3(3)
March 20, 1982 

 
Title
Calculation of the Magnetic Moments and the Dipolar Shifts for d1 and d2 Complexes in a Strong Ligand Field of Trigonal Symmetry
Author
Sangwoon Ahn, Hyuk Choon Suh, Jeong Soo Ko
Keywords
Abstract
A method to calculate the magnetic moments for d1 and d2 complexes in a strong crystal field of trigonal symmetry has been developed in this work choosing the trigonal axis (Ⅲ) as the quantization axis. The calculated magnetic moments using this method for d1 and d2 complexes in a strong trigonal ligand field fall in the range of the experimental values. The dipolar shifts for d1 and d2 complexes in a strong trigonal ligand field are also calculated using the calculated magnetic susceptibility components. The calculated values of the dipolar shifts also fall in the reasonable range.
Page
104 - 109
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