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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 3, Number 3
BKCSDE 3(3)
March 20, 1982 

 
Title
Transition-State Variation in the Solvolysis of Benzoyl Chlorides
Author
Gi-Ho Jeong, Hong-Lee Park
Keywords
Abstract
Solvolysis reactions of some substituted benzoyl chlorides were studied in ethanol-water, ethanol-trifluoroethanol and methanol-acetonitrile mixtures. Results showed that the reaction proceeds via an SN2 process in which bond formation is more advanced than bond cleavage. Comparison of the two models for predicting transition state variation indicated superior nature of the quantum mechanical model relative to the potential energy surface model.
Page
92 - 98
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