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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 3, Number 3
BKCSDE 3(3)
March 20, 1982

Title	Transition-State Variation in the Solvolysis of Benzoyl Chlorides
Author	Gi-Ho Jeong, Hong-Lee Park
Keywords
Abstract	Solvolysis reactions of some substituted benzoyl chlorides were studied in ethanol-water, ethanol-trifluoroethanol and methanol-acetonitrile mixtures. Results showed that the reaction proceeds via an SN2 process in which bond formation is more advanced than bond cleavage. Comparison of the two models for predicting transition state variation indicated superior nature of the quantum mechanical model relative to the potential energy surface model.
Page	92 - 98
Full Text	PDF

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