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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 3, Number 2
BKCSDE 3(2)
February 20, 1982

Title	The Facile Synthesis of Pentane-1,5-diamines from Glutaraldehyde and Secondary Amines with Tetracarbonylhydridoferrate
Author	Sang Chul Shim, Yoshihisa Watanabe
Keywords
Abstract	Ethanolic tetracarbonylhydridoferrate solution combined with glutaraldehyde is a very effective reducing agent for the selective transformation of two moles of secondary amines into pentane-1,5-diamine derivatives. A variety of aliphatic secondary amines react with ferrate-glutaraldehyde at room temperature under carbon monoxide to give the corresponding N-substituted pentane-1,5-diamines in reasonable yields.
Page	76 - 78
Full Text	PDF

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