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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 2, Number 2
BKCSDE 2(2)
February 20, 1981

Title	SN2 Transition State Variation in the Benzenesulfonyl Chloride Sovolysis
Author	Ikchoon Lee, In Sun Koo, Han Keun Kang
Keywords
Abstract	For solvolyses of benzenesulfonylchlorides we determined transfer enthalpies of transition states, and solvent (TFE + EtOH) and substituent effects on rates. We have used the More O'Ferrall plots to show that transition states variation caused by solvent and substituent changes is consistent with an associative SN2 mechanism for the nucleophilic substitution reaction of benzenesulfonylchlorides.
Page	41 - 45
Full Text	PDF

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