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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 1, Number 1
BKCSDE 1(1)
January 20, 1980 

 
Title
Kinetics of Cl Atom Reactions. Anomaluous Fluorescence Behavior of Some Cl Atomic Transitions
Author
Kwang Yul Choo
Keywords
Abstract
During the study of the kinetics of Cl atom reactions by atomic fluorescence method we observed anomalous fluorescence emission for some atomic transitions. Instead of usual decrease of the fluorescence intensity by adding substrate, 1363 A transition (2P°3/2 → 2P1/2) intensity increased by adding substrate. From the normally behaved fluorescence lines the absolute rate constant for the reaction, Cl + CH3Cl →, was found to be 4.2 × 10-13 cc/molecule sec at 20℃.
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