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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 35, Number 6
BKCSDE 35(6)
June 20, 2014 

CdII MOFs Constructed Using Succinate and Bipyridyl Ligands: Photoluminescence and Heterogeneous Catalytic Activity
Myoung Mi Lee, Ha-Yeong Kim, In Hong Hwang, Jeong Mi Bae, Cheal Kim*, Chul-Hyun Yo, Youngmee Kim*, Sung-Jin Kim
CdII MOFs, Succinate, Photoluminescence, Heterogeneous catalysts, Transesterification
Four CdII MOFs, [Cd2(μ-succinate)2(H2O)2]·H2O (1A), [Cd2(μ-succinate)2(μ-4,4'-bpy)2]·H2O (1B), [{Cd2(μ- succinate)2}(μ-bpa)2{Cd(H2O)2}(NO3)2]·H2O (2), and [Cd(μ-succinate)(μ-bpp)2]·2H2O (3), with various bipyridyl ligands (4,4'-bipyridine (4,4'-bpy), 1,2-bis(4-pyridyl)ethane (bpa), and 1,3-bis(4-pyridyl)propane (bpp)) were prepared, and their structures were determined using X-ray crystallography. The structures and dimensionalities of CdII–(succinate) compounds varied depending on the auxiliary ligands. Heterogeneous catalytic activity for transesterification reactions, photoluminescence and the thermal stabilities of these compounds were also examined.
1777 - 1783
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