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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 34, Number 10
BKCSDE 34(10)
October 20, 2013 

An Efficient Synthesis of Poly-Substituted Phenols and Pyridines from Morita-Baylis-Hillman Acetates and Diethyl Oxalacetate
Jin Yu, Ko Hoon Kim, Hyun Ju Lee, Jae Nyoung Kim*
Phenols, Pyridines, Morita-Baylis-Hillman acetates, Diethyl oxalacetate
Various phenol derivatives were synthesized in a one-pot reaction from MBH acetates and sodium diethyl oxalacetate via a [4C+2C] cyclization protocol. In addition, some pyridine derivatives could also be synthesized using the same starting materials, by isolating the SN2' reaction intermediate and performing the cyclization with NH4OAc.
3027 - 3032
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