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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 34, Number 10
BKCSDE 34(10)
October 20, 2013 

A Manganese Coordination Polymer and a Palladium Molecular Compound of 3−Pyridinepropionic acid (HL): [MnL2(H2O)2] and trans-[Pd(HL)2Cl2]
Seo Young Im, Soon W. Lee*
Pyridyl-carboxylate terminals, Coordination polymer
Three coordination polymers, [ML2(H2O)2] (M = Co (1), Ni (2), Mn (3)), were prepared from metal acetates (M(CH3COO)2·4H2O) and 3−pyridinepropionic acid (HL = (3-py)–CH2CH2COOH) by solvent-layer methods. By contrast, a discrete molecular compound, trans-[Pd(HL)2Cl2] (4), was synthesized by replacing benzonitrile (PhCN) ligands in trans-[Pd(PhCN)2Cl2] with HL under microwave-heating conditions. Compounds 1–3 have a 2D framework, and compound 4 contains a square-planar Pd metal.
2947 - 2952
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