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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 34, Number 8
BKCSDE 34(8)
August 20, 2013 

A New Quinoline-Based Acylhydrazone for Highly Selective Fluorescence Recognition of Cu(II) and Sulfide in Aqueous Solution
Lijun Tang*, Pei Zhou, Zhikai Qi, Zhenlong Huang, Jia Zhao, Mingjun Cai
Copper detection, Sulfide recognition, Copper displacement, Acylhydrazone
A new quinoline-based acylhydrazone (1) has been synthesized and applied as a fluorescent probe. Probe 1 exhibits high selectivity and sensitivity to Cu2+ with fluorescence “ON-OFF” behavior in HEPES buffered (1‰ DMSO, HEPES 20 mM, pH = 7.4) solution. The on-site generated 1-Cu2+ complex displays excellent selectivity to sulfide ions with fluorescence “OFF-ON” performance through copper displacement approach.
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