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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 34, Number 2
BKCSDE 34(2)
February 20, 2013 

 
Title
BNBTS More than Brominating Agent: Green and One-pot Route for the C-N Bond Formation in Water from Alkenes
Author
Foad Kazemi*, Mazaher Abdollahi Kakroudi
Keywords
C-N bond formation, BNBTS, N-bromo sulfonamide, Bromo hydrin, Building blocks
Abstract
In this paper, in addition to introducing efficient method for bromohydrin and bromoether preparation, simple, green and efficient method to C-N bond formation from alkene and N,N'-Dibromo-N,N'-1,2-ethanediyl-bis(ptoluenesulfonamide) [BNBTS] in water was investigated. The reaction between alkenes, β-cyclodexterin, and BNBTS took place in water afterward, by making media basic; it will give the corresponding valuable building blocks in good yields (45-79%).
Page
500 - 504
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