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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 34, Number 1
BKCSDE 34(1)
January 20, 2013

Title	Kinetics of Reversible Consecutive Reactions
Author	Tae Jun Park
Keywords	Consecutive reaction, Unimolecular, Lindemann mechanism, Enzyme catalysis
Abstract	Rate equations are exactly solved for the reversible consecutive reaction of the first-order and the timedependence of concentrations is analytically determined for species in the reaction. With the assumption of pseudo first-order reaction, the calculation applies and determines the concentration of product accurately and explicitly as a function of time in the unimolecular decomposition of Lindemann and in the enzyme catalysis of Michaelis-Menten whose rate laws have been approximated in terms of reactant concentrations by the steady-state approximation.
Page	243 - 245
Full Text	PDF

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