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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 34, Number 1
BKCSDE 34(1)
January 20, 2013 

Preparation of Ruthenium Incorporated Heterogeneous Catalysts Using Hydroxyapatite as Catalytic Supports for Aerobic Oxidation of Alcohols
Sohee Kim, Jong-Hwa Jung, Dong-Hee Kim, Dong Kyun Woo, Joon B. Park*, Myong Yong Choi*, Ki-Young Kwon*
Aerobic oxidation, Heterogeneous catalysts, Hydroxyapatite, Surface
Three different kinds of hydroxyapatites (HAPs) having different sizes and compositions are prepared by hydrothermal and molten salt syntheses. Using the ion exchange reactions, ruthenium ions are incorporated on the surface of HAPs. The crystallinity, morphology and ruthenium contents are investigated by XRD, SEM, TEM and ICP. We found that smaller size of HAP having large amounts of ruthenium under ion exchange reaction shows higher catalytic activity for aerobic oxidation of alcohols.
221 - 224
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