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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 33, Number 8
BKCSDE 33(8)
August 20, 2012 

Study of the Resonance Structures of the Preionizing Spectrum of Molecular Hydrogen by Phase-Shifted Multichannel Quantum Defect Theory II
Chun-Woo Lee
Phase-shifted MQDT, Overlapping resonances, Preionization of H2, Interlopers
We obtain the general formulation which can handle the rotational preionization spectrum of H2 in the region above its H2 + ionization threshold (2 +g, v+ = 0, N+ = 0), converging toward its rotationally excited (v+ = 0, N+ = 2) limit and perturbed by the vibrationally excited levels 7pπ v = 1 and 5pπ v = 2. The formulation is based on phase-shifted multichannel quantum-defect theory. With this formulation, resonance structures are analyzed in detail.
2657 - 2668
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