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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 33, Number 5
BKCSDE 33(5)
May 20, 2012 

Open Tubular Molecular Imprinted Polymer Fabricated in Silica Capillary for the Chiral Recognition of Neutral Enantiomers in Capillary Electrochromatography
Song Hee Yang, Shabi Abbas Zaidi, Won Jo Cheong,* Zeid A. ALOthman, Abdullah M. ALMajid
Neutral template, Molecule imprinted polymer, Chiral separation, Open tubular capillary, Capillary electrochromatography
In this study, we have expanded the applicability of the pre-established generalized preparation protocol to MIPs with a neutral template. The (4S,5R)-4-methyl-5-phenyl-2-oxazolidinone MIP layer was formed inside a pretreated and silanized fused silica capillary, and its chiral separation performance was examined. Optimization of chiral separation was also carried out. This is the very first report of somewhat successful application of the generalized preparation protocol to a MIP with a genuine neutral template.
1664 - 1668
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