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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 33, Number 4
BKCSDE 33(4)
April 20, 2012 

 
Title
A Mild and Efficient Tris(pentafluorophenyl)borane-catalyzed Sakurai Allylation of N-Benzyloxycarbonylamino p-Tolylsulfone with Allyltrimethylsilane
Author
Ponnaboina Thirupathi,* Lok Nath Neupane, Keun-Hyeung Lee*
Keywords
N-Benzyloxycarbonylamino p-Tolylsulfone, Tris(pentafluorophenyl)borane, Allyltrimethylsilane, Allylation, N-Cbz-homoallylic amines
Abstract
Tris(pentafluorophenyl)borane, B(C6F5)3, was found to be an efficient catalyst for synthesis of N-Cbzhomoallylic amines using Sakurai allylation of N-benzyloxycarbonyl-amino p-tolylsulfones with allyltrimethylsilane.
Page
1275 - 1278
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