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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 33, Number 1
BKCSDE 33(1)
January 20, 2012 
 
Title
 Morita-Baylis-Hillman Route to Dimethyl 2,3-Dihydrobenzo[b]oxepine-2,4- dicarboxylates and Methyl 2-(2-Carbomethoxybenzo[b]furan-3-yl)propanoates from Salicylaldehydes
Author
 Sang-Hyun Ahn, Seung Soon Jang, Young Keun Kim, Kee-Jung Lee *
Keywords
 Morita-Baylis-Hillman, SN2-SN2' Reaction, 2,3-Dihydrobenzo[b]oxepines, Benzo[b]furans, Methyl (2-formylphenoxy)acetates.
Abstract
 A new synthetic method for dimethyl 2,3-dihydrobenzo[b]oxepine-2,4-dicarboxylates and methyl 2-(2- carbomethoxybenzo[b]furan-3-yl)propanoates by an intramolecular conjugate displacement reaction or an SN2 reaction of acetates of Morita-Baylis-Hillman adducts of methyl (2-formylphenoxy)acetates has been described.
Page
 233 - 242
Full Text
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