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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 32, Number 5
BKCSDE 32(5)
May 20, 2011 

Synthesis and Characterization of 9,9'-Diethyl-2-diphenylaminofluorene Derivatives as Blue Fluorescent Materials for OLEDs
Suhyun Oh, Kum Hee Lee, Ji Hoon Seo, Young Kwan Kim,*, Seung Soo Yoon*
Blue, Fluorescent OLEDs, Diphenylaminofluorene derivatives
Blue fluorescent materials based on 9,9'-diethyl-2-diphenylaminofluorene derivatives were synthesized and characterized. These materials were used as the blue dopant materials for the emitting layer of organic lightemitting diode devices with the following device structure: ITO/DNTPD (40 nm)/NPB (20 nm)/MADN: dopants (2%, 20 nm)/Alq3 (40 nm)/Liq (1.0 nm)/Al. All devices exhibited highly efficient blue emission. One of these devices exhibited a maximum luminance, luminous efficiency, power efficiency and CIE x, y coordinates of 8400 cd/m2, 8.10 cd/A at 20 mA/cm2, 3.36 lm/W at 20 mA/cm2 and (0.151, 0.159), respectively. A deep blue device with CIE coordinates of (0.152, 0.139) showed the maximum luminance, luminous efficiency and power efficiency of 8630 cd/m2, 6.31 cd/A at 20mA/cm2 and 2.62 lm/W at 20 mA/cm2, respectively.
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