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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 32, Number 4
BKCSDE 32(4)
April 20, 2011

Title	A New Acetate Selective Polyamine Receptor Based on Anthracene and 4-Nitrophenyl Group
Author	Sung Kyu Lee, Jongmin Kang *
Keywords	Anion receptor, Polyamine receptor, Hydrogen bond
Abstract	A new amine receptor 2 utilizing anthracene and nitrophenyl group as signaling group was designed and synthesized. The receptor 2 only utilizes four amine N-H's and 9-anthracenyl hydrogen to bind anions. The receptor 2 can bind anions through hydrogen bonds with a selectivity of CH3CO2 − > H2PO4 − > F− > C6H5CO2 − > Cl− in highly polar solvent such as DMSO without protonation of amine.
Page	1228 - 1230
Full Text	PDF

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