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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 31, Number 12
BKCSDE 31(12)
December 20, 2010 

Selective oxidation of olefins catalyzed by polymer-anchored nickel(II) complex in water medium
Manirul Islam*, Dildar Hossain, Paramita Mondal, Anupam Singha Roy, Sanchita Mondal, Manir Mobarak
Chloromethylated polystyrene, Nickel (II) complex, Olefin oxidation, Water, TBHP
Selective oxidation of olefins has been carried out in water medium with tert-butylhydroperoxide (TBHP, 70% aqueous) as an oxidant using polymer-anchored Ni(II) complex as a catalyst. Several parameters were varied to optimize the reaction conditions. Under the optimized reaction conditions olefins gave selectively allylic oxidation products. The present polymer anchored Ni(II) complex can be recycled five times without any appreciable loss in catalytic activity.
3765 - 3770
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