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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 31, Number 12
BKCSDE 31(12)
December 20, 2010 

Synthesis of Some Novel Pyrimidine Derivatives and Investigation of their Electrochemical Behavior
Esvet Akbas*, Abdulkadir Levent,*, Selçuk Gümü&351;, Mehmet Rauf Sümer, &304;nci Akyazı
2-Iminopyrimidines, 2-Thioxopyrimidine, Biginelli cyclocondensation, Electrochemical properties
2-Iminopyrimidines (1a-e) and 2-thioxopyrimidine (2) were synthesized using the Biginelli three component cyclocondensation reaction of an appropriate β-diketone, arylaldehyde, and guanidine (for 1a-e) or thiourea (for 2). The electrochemical properties of the novel systems were investigated by CV and DPV. Moreover, B3LYP/6-31G(d,p) method was applied to the present structures in order to gather some structural and physicochemical data.
3632 - 3638
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