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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 31, Number 7
BKCSDE 31(7)
July 20, 2010 
 
Title
 Nonisothermal Decomposition Reaction Kinetics, Specific Heat Capacity, Thermodynamic Properties and Adiabatic Time-to-explosion of 4-Amino-1,2,4-triazole Copper Complex
Author
 Yinghui Ren*, Dan Li, Jianhua Yi, Fengqi Zhao, Haixia Ma, Kangzhen Xu, Jirong Song
Keywords
 4-Amino-1,2,4-triazole copper complex (4-ATzCu), Nonisothermal kinetics, Specific heat capacity, Thermodynamic property, Adiabatic time-to-explosion
Abstract
 4-Amino-1,2,4-triazole copper complex (4-ATzCu) was synthesized, and its thermal behaviors, nonisothermal decomposition reaction kinetics were studied by DSC and TG-DTG techniques. The thermal decomposition reaction kinetic equation was obtained as: dα / dt =1022.01 (1-α )[-ln(1-α )]1/3 exp(-2.75×104 /T) . The standard mole specific heat capacity of the complex was determined and the standard molar heat capacity is 305.66 J·mol-1·K-1 at 298.15 K. The entropy of activation ( ΔS ≠ ), enthalpy of activation (ΔH ≠), and Gibbs free energy of activation ( ΔG≠) are calculated as 171.88 J·mol-1·K-1, 225.81 kJ·mol-1 and 141.18 kJ·mol-1, and the adiabatic time-to-explosion of the complex was obtained as 389.20 s.
Page
 1988 - 1992
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