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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 31, Number 3
BKCSDE 31(3)
March 20, 2010 

 
Title
Enantioselective Total Synthesis of (-)-Clavosolide A and B
Author
Jung Beom Son, Si Nae Kim, Na Yeong Kim, Min ho Hwang, Wonsun Lee, Duck Hyung Lee*
Keywords
Enantioselective total synthesis, Clavosolide A, Clavosolide B
Abstract
Enantioselective total synthesis of (-)-clavosolide A and B was reported in full including the synthesis of proposed structure of (-)-clavosoldie A (1), revised structure of (-)-clavosoldie A (5), and revised structure of (-)-clavosoldie B (6). The relative and absolute stereochemistries of the natural products were confirmed unambiguously by comparing the optical rotation values and 1H and 13C NMR spectra of them.
Page
653 - 663
Full Text
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