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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 31, Number 2
BKCSDE 31(2)
February 20, 2010 

 
Title
Synthesis of Li4Ti5O12 Thin Film with Inverse Hemispheric Structure
Author
Sung Je Lee, Kwang Hee Jung, Bo Gun Park, Ho Gi Kim, Yong Joon Park*
Keywords
Template, Inverse hemispheric structure, Sol-gel, Li4Ti5O12, Thin film
Abstract
Li4Ti5O12 thin film with inverse hemispheric structure was fabricated on a Pt/Ti/SiO2/Si substrate by the sol-gel and dip coating method for use as an anode for 3-dimensional (3D) thin-film batteries. Polystyrene (PS) beads of 400 nm diameter were used to prepare the template for the inverse hemispheric structure. A coating solution prepared using precursor sources was dropped on the template-deposited substrates, which were then calcinated at 400 oC. The template was removed by calcination, and the inverse hemispheric structure was successfully formed by an annealing process. The cyclic performance during high-rate charge/discharge processes of the Li4Ti5O12 film with inverse hemispheric structure was superior to that of the flat Li4Ti5O12 film.
Page
360 - 364
Full Text
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