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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 11
BKCSDE 30(11)
November 20, 2009 

 
Title
Photodissociation of Nitrous Oxide by Slice Ion Imaging: The Stagnation Pressure Dependence
Author
Nu Ri Cheong, Hye Sun Park, Sang Hwan Nam, Seung Keun Shin, Soo Gyeong Cho, Hai Whang Lee, Jae Kyu Song*, Seung Min Park*
Keywords
Slice ion imaging, Photodissociation, Cluster
Abstract
Photodissociation of nitrous oxide near 203 nm has been studied by a combination of high resolution slice ion imaging technique and (2+1) resonance-enhanced multiphoton ionization (REMPI) spectroscopy of N2(X1Σg+) via the (a″1Σg+) state. We have measured the recoil velocity and angular distributions of N2 fragments by ion images of the state-resolved photofragments. The N2 fragments were highly rotationally excited and the NN-O bond dissociation energy was determined to be 3.635 eV. Also, we investigated the photofragment images from the photodissociation of N2O clusters with various stagnation pressures.
Page
2661 - 2664
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