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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 10
BKCSDE 30(10)
October 20, 2009 

New Route to N-Formylation of Primary Amines with Amino Acids as a Source of CO Using Polyaniline Catalyst
Jeong Soo Ahn, Ki Whan Chi, Ho Yun Hwang, Kwang Sun Ryu, Chan Woo Lee*
N-Formylation, CO generation, Amino acid, Polyaniline emeraldine salt
The treatment of primary amines with amino acids as a CO source in the presence of polyaniline emeraldine salts bring about N-formylation to give the corresponding formamides. This route to N-formylation methodology of primary amine represents the first reported example of a CO-transfer via radical mechanism by highly nanoporous polyaniline emeraldine salts catalyst.
2377 - 2380
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