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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 6
BKCSDE 30(6)
June 20, 2009 

 
Title
Highly Enantioselective Rh-catalyzed Transfer Hydrogenation of α-Functionalized Arylketones
Author
Do Min Lee, Se Hun Kwak, Kee In Lee*
Keywords
Asymmetric transfer hydrogenation, α-Mesyloxy arylketone, Arylethandiol
Abstract
Asymmetric transfer hydrogenation of α-functionalized arylketones has been studied. The chiral Rh-catalyst effectively performed in transfer hydrogenation of α-mesyloxyketones with an azeotropic mixture of formic acid/triethylamine to produce optically active 1-arylethandiols with excellent enantioselectivity.
Page
1317 - 1324
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