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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 29, Number 9
BKCSDE 29(9)
September 20, 2008 
 
Title
 Pyridinolysis of O-Aryl Phenylphosphonochloridothioates in Acetonitrile
Author
 Bilkis Jahan Lumbiny, Keshab Kumar Adhikary, Bon Su Lee*, Hai Whang Lee*
Keywords
 O-Aryl phenylphosphonochloridothioates, Pyridinolysis, Cross-interaction constant, Deuterium kinetic isotope effect
Abstract
 The kinetics and mechanism of the reactions of Y-O-aryl phenylphosphonochloridothioates with X-pyridines are investigated in acetonitrile at 35.0 oC. The negative value of the cross-interaction constant, ρXY = ?0.46, indicates that the reaction proceeds by concerted SN2 mechanism. The observed kH/kD values involving d-5 pyridine (C5D5N) nucleophiles are greater than unity (1.05-1.11). The net primary deuterium kinetic isotope effects, (kH/kD)net = 1.28-1.35, excluding the increased pKa effect of d-5 pyridine are obtained. The transition state with a hydrogen bond between the leaving group Cl and the hydrogen (deuterium) atom in the C-H(D) is suggested for the studied reaction system.
Page
 1769 - 1773
Full Text
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