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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 29, Number 4
BKCSDE 29(4)
April 20, 2008 
 
Title
 Formation of Complex XeHCl+ in the Xe+ + HCl Collision
Author
 Jongbaik Ree*, Yoo Hang Kim, Hyung Kyu Shin
Keywords
 Collision-induced complex, XeHCl+, Xe+, HCl
Abstract
 The formation of complex XeHCl+ in the collision-induced reaction of Xe+ with HCl has been studied by use of classical dynamics procedures using the London-Eyring-Polanyi-Sato empirical potential energy surfaces. A small fraction of trajectories on the Xe+ + HCl and Xe + HCl+ surfaces lead to the formation of complex XeHCl+ with life-times of 1-2 ps which is long enough to survive many rotations before redissociating back to the reactant state. The formation of complex XeHCl+ occurs mainly from collision angle of Θ = 45°.
Page
 795 - 798
Full Text
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