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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 29, Number 3
BKCSDE 29(3)
March 20, 2008 

Coordination Polymers Consisting of Unusual Motifs. Synthesis and Properties of Silver(I) and Copper(II) Complexes of Triethanolaminetriisonicotinate
Tae Hwan Noh, Jung Woon Lee, Young-A Lee, Ji Eun Lee, Shim Sung Lee, Ok-Sang Jung*
Anion exchange, Copper(II) complexes, Crystal structures, One dimensional coordination polymers, Silver(I) complexes
Reaction of AgNO3 with triethanolaminetriisonicotinate (L) produces 1 D coordination polymer of [Ag3(L)2](NO3)3 and the same treatment of Cu(NO3)2 with L gives 1D coordination polymer of [Cu(L)2](NO3)2. The nonrigid triethanolaminetriisonicotinate acts as a μ 3-bridged tridentate for [Ag3(L)2]- (NO3)3 and a μ 2-bridged bidentate for [Cu(L)2](NO3)2 to produce unusual motifs. The NO3- anions can be smoothly exchanged by PF6- anions in an aqueous suspension without destruction of the skeletal structure.
562 - 566
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