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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 28, Number 11
BKCSDE 28(11)
November 20, 2007

Title	Solvent-free Microwave-Assisted Ortho-Alkylation of Aromatic Ketimine with Acrylic Acid Derivatives by Rh(I) Catalyst
Author	Eun-Ae Jo, Jeong-Ae Ahn, Chul-Ho Jun*
Keywords	ortho-alkylation, Microwave, Rhodium, Homogeneous catalyst, Ketimine
Abstract	Microwave(MW)-assisted ortho-alkylation of aromatic imine with acrylic acid derivatives was performed in the presence of a (PPh₃)₃RhCl catalyst, and corresponding ortho-alkylated ketones were obtained after hydrolysis of the resulting ketimines. This solventless MW-assisted ortho-alkylation was highly efficient compared with conventional heating, probably due to the specific MW effect.
Page	2020 - 2024
Full Text	PDF

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