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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 28, Number 10
BKCSDE 28(10)
October 20, 2007

Title	Synthesis and Characterization of Aliphatic Polyether Dendrons Based on Polystyrene Peripheries
Author	Jie Song, Hyun-Yu Kim, Byoung-Ki Cho*
Keywords	Aliphatic polyether dendrons, Polymeric peripheries, Anionic polymerization, Convergent synthesis
Abstract	The synthesis of well-defined dendrons based on aliphatic polyether dendritic cores and glassy polystyrene peripheries is described. The synthetic route involves a combination of living anionic polymerization and a stepwise convergent method consisting of iterative Williamson etherification and hydroboration/oxidation reactions. On the basis of molecular weight, as characterized by gel permeation chromatography (GPC), the first generation dendron (Generation-1) shows a random coil conformation like a linear polystyrene, while higher generations (Generation-2 and 3) reveal globular forms in solution.
Page	1771 - 1776
Full Text	PDF

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