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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 28, Number 3
BKCSDE 28(3)
March 20, 2007

Title	Novel Linking Ligand Containing Sulfur-Donor Atoms and Its Compounds of Palladium and Silver
Author	Hee K. Lee, Soon W. Lee*
Keywords	Linking ligand containing sulfur donor atoms, Silver coordination polymers
Abstract	A linking ligand containing sulfur donor atoms in the terminal thiophene rings, 1,2-bis(thiophen-2-ylmethylene) hydrazine (L), was prepared by Schiff-base condensation. Ligand L reacted with [PdCl₂(NCPh)₂] to produce a molecular Pd compound [PdL₂Cl₂] (1). On the other hand, it reacted with AgNO₃ and AgClO₄ to produce a 2-D network [AgL_0.5(NO₃)] (2) and a 1-D polymer [AgL]ClO₄ (3), respectively, whose structures are based on secondary intermolecular forces such as H-bonding, van der Waals interaction, and π-π stacking. Polymer 2 exhibited photoluminescence at room temperature in the solid state.
Page	421 - 426
Full Text	PDF

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