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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 27, Number 9
BKCSDE 27(9)
September 20, 2006 
 
Title
 Photoreactions of (2-Alkoxymethylphenyl)pentamethyldisilanes
Author
 Seung Ki Park
Keywords
 (2-Hydroxymethylphenyl)pentamethyldisilane, (2-Acetoxymethylphenyl)pentamethyldisilane, (2-Allyloxymethylphenyl)pentamethyldisilane, Silene
Abstract
 Photolysis of (2-hydroxymethylphenyl)pentamethyldisilane 1 in methanol provides a novel intramolecular photoproduct 4 via silene intermediate 2 but the photoreaction of (2-acetoxymethyl- or allyloxymethylphenyl) pentamethyldisilanes 5 or 10 in methanol affords unexpected photoproducts 8 or 13, respectively, instead of expected intramolecular photoproducts.
Page
 1305 - 1309
Full Text
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